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posted by  edelpink on 11/5/2009 1:14:01 AM  |  status: Live  |  Earned Karma: 60

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Course Textbook Chapter Problem Needs by
Thermodynamics N/A Phase Equilibrium N/A 11/6/2009 at 12:00:00 PM
Question Details:

Solid white phosphorus has a conventional standard Gibbs energy of zero at 25°C. The melting point is 44.2°C and ?H°fusion=2510J/mol P4. The vapor pressure of white phosphorus has the values:

t/°C       76.6       128.0     197.3

                                               p/Torr  1             10           100

a)      Calculate ?H°vapor of liquid phosphorus

b)      Calculate boiling point of the liquid

c)       Calculate the vapor pressure at the melting point

d)      Assuming that solid, liquid and gaseous phosphorus are in equilibrium at the melting point, calculate the vapor pressure of solid white phosphorus at 25°C.

e)      Calculate the standard Gibbs energy of gaseous phosphorus at 25°C.


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